Ab-initio Structure and Thermodynamics of the RPBE-D3 Water/Vapor Interface by Neural-Network Molecular Dynamics

Author(s)
Oliver Wohlfahrt, Christoph Dellago, Marcello Sega
Abstract

Aided by a neural network representation of the density functional theory potential energy landscape of water in the Revised Perdew-Burke-Ernzerhof approximation corrected for dispersion, we calculate several structural and thermodynamic properties of its liquid/vapor interface. The neural network speed allows us to bridge the size and time scale gaps required to sample the properties of water along its liquid/vapor coexistence line with unprecedented precision.

Organisation(s)
Computational and Soft Matter Physics
External organisation(s)
Forschungszentrum Jülich
Journal
Journal of Chemical Physics
Volume
153
No. of pages
6
ISSN
0021-9606
DOI
https://doi.org/10.1063/5.0021852
Publication date
2020
Peer reviewed
Yes
Austrian Fields of Science 2012
103015 Condensed matter, 103043 Computational physics, 103006 Chemical physics, 103029 Statistical physics
Keywords
ASJC Scopus subject areas
General Physics and Astronomy, Physical and Theoretical Chemistry
Portal url
https://ucrisportal.univie.ac.at/en/publications/b190e6b0-9ac3-4586-a91b-86f7c750ecaa