Rescaling of structural length scales for "soft effective segment" representations of polymers in good solvent

Author(s)
Ivan Coluzza, Barbara Capone, Jean-Pierre Hansen
Abstract

It is shown by simple scaling arguments that the structural length scales of semi-dilute polymer solutions, calculated from coarse-grained "soft effective segment" representations of long polymers, need to be rescaled by a single, well-defined scaling factor to match the corresponding properties of the underlying microscopic polymer model. The validity of this rescaling is illustrated by extensive Monte Carlo simulations of the density profiles and average height of stretched polymer brushes. PACS numbers: 68.47.Mn, 68.47.Pe, 61.25.Hq, 82.35.Lr

Organisation(s)
Computational and Soft Matter Physics
External organisation(s)
University of Cambridge
Journal
Soft Matter
Volume
7
Pages
5255-5259
No. of pages
5
ISSN
1744-683X
DOI
https://doi.org/10.1039/c1sm05335c
Publication date
2011
Peer reviewed
Yes
Austrian Fields of Science 2012
103002 Acoustics
Portal url
https://ucrisportal.univie.ac.at/en/publications/887d346e-e339-4c56-852c-64a9b0c42473