Rheology of a Nanopolymer Synthesized through Directional Assembly of DNA Nanochambers, for Magnetic Applications
- Author(s)
- Deniz Mostarac, Sofia S. Kantorovich
- Abstract
We present a numerical study of the effects of monomer shape and magnetic nature of colloids on the behavior of a single magnetic filament subjected to the simultaneous action of shear flow and a stationary external magnetic field perpendicular to the flow. We find that based on the magnetic nature of monomers, magnetic filaments exhibit a completely different phenomenology. Applying an external magnetic field strongly inhibits tumbling only for filaments with ferromagnetic monomers. Filament orientation with respect to the flow direction is in this case independent of monomer shape. In contrast, reorientational dynamics in filaments with superparamagnetic monomers are not inhibited by applied magnetic fields, but enhanced. We find that the filaments with spherical, superparamagnetic monomers, depending on the flow and external magnetic field strength, assume semipersistent, collapsed, coiled conformations, and their characteristic time of tumbling is a function of field strength. However, external magnetic fields do not affect the characteristic time of tumbling for filaments with cubic, superparamagnetic monomers, but increase how often tumbling occurs.
- Organisation(s)
- Computational and Soft Matter Physics, Research Platform MMM Mathematics-Magnetism-Materials
- Journal
- Macromolecules
- Volume
- 55
- Pages
- 6462–6473
- No. of pages
- 12
- ISSN
- 0024-9297
- DOI
- https://doi.org/10.1021/acs.macromol.2c00738
- Publication date
- 07-2022
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 103043 Computational physics, 103023 Polymer physics, 103017 Magnetism
- Keywords
- ASJC Scopus subject areas
- Materials Chemistry, Polymers and Plastics, Inorganic Chemistry, Organic Chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/801a092f-5679-40fa-8f96-2274624b2b34