Magnetostatic response and field-controlled haloing in binary superparamagnetic mixtures

Author(s)
Andrey A. Kuznetsov, Sofia S. Kantorovich
Abstract

Nowadays, magnetoresponsive soft materials, based not simply on magnetic nanoparticles but rather on multiple components with distinct sizes and magnetic properties in both liquid and polymeric carriers, are becoming more and more widespread due to their unique and versatile macroscopic response to an applied magnetic field. The variability of the latter is related to a complex interplay of the magnetic interactions in a highly nonuniform internal field caused by spatial inhomogeneity in multicomponent systems. In this work, we present a combined analytical and simulation study of binary superparamagnetic systems containing nanoclusters and dispersed single-domain nanoparticles in both liquid and solid carrier matrices. We investigate the equilibrium magnetic response of these systems for wide ranges of concentrations and interaction energies. It turns out that, while the magnetization of a binary solid can be both above and below that of an ideal superparamagnetic gas, depending on the concentration of the dispersed phase and the interparticle interactions, the system in a liquid carrier is highly magnetically responsive. In liquid, a spatial redistribution of the initially homogeneously dispersed phase in the vicinity of the nanocluster is observed, an effect that is reminiscent of the so-called haloing effect previously observed experimentally on micro- and milliscales.

Organisation(s)
Computational and Soft Matter Physics, Research Platform MMM Mathematics-Magnetism-Materials
Journal
Physical Review E
Volume
108
No. of pages
11
ISSN
2470-0045
DOI
https://doi.org/10.1103/PhysRevE.108.064603
Publication date
12-2023
Peer reviewed
Yes
Austrian Fields of Science 2012
103043 Computational physics
ASJC Scopus subject areas
Condensed Matter Physics, Statistical and Nonlinear Physics, Statistics and Probability
Portal url
https://ucrisportal.univie.ac.at/en/publications/611b27fd-65ae-4237-88b7-6d543f9689d4