Nanoparticle Shape Influences the Magnetic Response of Ferro-Colloids

Author(s)
Joe G. Donaldson, Elena S. Pyanzina, Sofia S. Kantorovich
Abstract

The interesting magnetic response of conventional ferro-colloid has proved extremely useful in a wide range of technical applications. Furthermore, the use of nano/micro- sized magnetic particles has proliferated cutting-edge medical research, such as drug targeting and hyperthermia. In order to diversify and improve the application of such systems, new avenues of functionality must be explored. Current efforts focus on incorporating directional interactions that are surplus to the intrinsic magnetic one. This additional directionality can be conveniently introduced by considering systems composed of magnetic particles of different shapes. Here we present a combined analytical and simulation study of permanently magnetized dipolar superball particles; a geometry that closely resembles magnetic cubes synthesized in experiments. We have focused on determining the initial magnetic susceptibility of these particles in dilute suspensions, seeking to quantify the effect of the superball shape parameter on the system response. In turn, we linked the computed susceptibilities to the system microstructure by analyzing cluster composition using a connectivity network analysis. Our study has shown that by increasing the shape parameter of these superball particles, one can alter the outcome of self-assembly processes, leading to the observation of an unanticipated decrease in the initial static magnetic susceptibility.

Organisation(s)
Computational and Soft Matter Physics
External organisation(s)
Ural Federal University
Journal
ACS Nano
Volume
11
Pages
8153-8166
No. of pages
14
ISSN
1936-0851
DOI
https://doi.org/10.1021/acsnano.7b03064
Publication date
08-2017
Peer reviewed
Yes
Austrian Fields of Science 2012
103017 Magnetism, 210006 Nanotechnology
Keywords
ASJC Scopus subject areas
General Engineering, General Physics and Astronomy, General Materials Science
Portal url
https://ucrisportal.univie.ac.at/en/publications/2b5bc522-7510-4a3d-b2f5-40721e71c5bf