The effect of links on the interparticle dipolar correlations in supramolecular magnetic filaments

Author(s)
Pedro A. Sánchez, Joan J. Cerdà, Tomas M. Sintes, Alexey O. Ivanov, Sofia Kantorovich
Abstract

We present a combined computational and analytical study of supramolecular magnetic filaments, i.e., permanently linked chains of ferromagnetic nanocolloids. We put forward two different models for the interparticle connectivity within the chain. In the first model, the magnetic dipoles of the particles are free to rotate independently from the permanent links. The second model penalises the misalignment of the dipoles by coupling their orientations to the chain backbone. We show that the effect of the long-range magnetic dipolar interactions on the zero field net magnetic moment of the chain becomes less significant in the second case. However, the overall magnetic response in the model of freely rotating dipoles is much weaker.

Organisation(s)
Computational and Soft Matter Physics
External organisation(s)
Ural Federal University, University of the Balearic Islands
Journal
Soft Matter
Volume
11
Pages
2963-2972
No. of pages
10
ISSN
1744-683X
DOI
https://doi.org/10.1039/C5SM00172B
Publication date
02-2015
Peer reviewed
Yes
Austrian Fields of Science 2012
103015 Condensed matter, 103023 Polymer physics, 103006 Chemical physics, 103017 Magnetism
ASJC Scopus subject areas
Condensed Matter Physics, General Chemistry
Portal url
https://ucrisportal.univie.ac.at/en/publications/0bc9be07-9e6c-4eaf-a46e-202c0c16bc0e